World Library  
Flag as Inappropriate
Email this Article

Interstellar nitrogen monohydride

Article Id: WHEBN0020737460
Reproduction Date:

Title: Interstellar nitrogen monohydride  
Author: World Heritage Encyclopedia
Language: English
Subject: NH, List of interstellar and circumstellar molecules
Collection:
Publisher: World Heritage Encyclopedia
Publication
Date:
 

Interstellar nitrogen monohydride

Nitrogen monohydride (NH) is a simple compound that has been detected in interstellar space.

History

One of the earliest papers on the NH molecule was in 1976 by Richard M. Crutcher and William D. Watson. They were still trying to pinpoint the absorption line for NH. There was an already theoretical upper limit of 0.3mÅ, but they needed a more exact figure. They thought that NH should normally be produced on grains (directly or indirectly) at about the same rate per atom as OH (hydroxyl) and possibly CH (methine). However, its formation by gas phase reactions was extremely slow and could be neglected in comparison with the possible rate for surface reactions. The presence or absence of NH at a certain abundance level could then be interpreted as evidence concerning the importance of surface reactions. Their hope was to find the abundance ratio between NH and OH. They weren’t able to find the absorption line for NH. Therefore the observations were inconclusive.[1]

Interstellar NH was discovered in outer space for the first time in 1991 by D. M. Meyer and K. C. Roth. NH is reported in the diffuse clouds toward Zeta Per and HD 27778 from high-resolution high S/N spectra of the NH Å 3Pi-X 3Sigma (0,0) absorption band near 3358 Å. These observations represent the first detection of this molecule anywhere in the interstellar medium.[2]

Shortly after NH’s discovery, Wagenblast, R. Williams, D. A. Millar, T. J. Nejad, and L. A. M., did some work on NH in 1992. They noticed that the observation of NH in the interstellar clouds towards Per and HD 27778 could not be explained with conventional gas-phase chemistry models. They proposed a non-equilibrium model for the Per cloud, which incorporated grain-surface production of NH and OH would be able to reproduce the abundances of all the observed species (except CH+) accurately. A pure gas-phase model and cloud interface model, in which NH and CH+ were formed in a warm and tenuous environment, failed to explain the observed high abundance of CN. Hence, the observations of NH in Per and HD 27778 provided evidence for the presence of grain-surface reactions leading to molecules other than H2.

At the end of their research, they concluded that even though the gas-phase formation of NH is given a large rate coefficient, NH was calculated to be underabundant with respect to the observations by a factor of 30. From this they discovered that a cold environment with a temperature of about 30K favored an efficient production of CN from NH within the diffuse cloud.[3]

Chemistry

Chemical reactions[4][5][6]
Reaction Rate Constant Rate/[H2]2
N + H- → NH + e- 1x10−9 3.5x10−18
NH2 + O → NH + OH 2.546x10−13 1.4x10−13
NH2+ + e- → NH + H 3.976x10−7 2.19x10−21
NH3+ + e- → NH + H + H 8.49x10−7 2.89x10−19
NH + N → N2 + H 4.98x10−11 4.36x10−16
NH + O → OH + N 1.16x10−11 1.54x10−14
NH + C+ → CN+ + H 7.8x10−10 4.9x10−19
NH + H3+ → NH2+ + H2 1.3x10−9 3.18x10−19
NH + H+ → NH+ + H 2.1x10−9 4.05x10−20

Within diffuse clouds H- + N → NH + e- is a major formation mechanism. Near chemical equilibrium important NH formation mechanisms are recombinations of NH2+ and NH3+ ions with electrons. Depending on the radiation field in the diffuse cloud, NH2 can also contribute.

NH is destroyed in diffuse clouds by photodissociation and photionization. In dense clouds NH is destroyed by reactions with atomic Oxygen and Nitrogen. O+ and N+ form OH and NH in diffuse clouds. NH is involved in creating N2, OH, H, CN+, CH, N, NH2+,NH+ for the interstellar medium.

Significance

NH has been reported in the diffuse interstellar medium but not in dense molecular clouds.[7] The purpose for detecting NH is often to get a better estimate of the rotational constants and vibrational levels of NH.[8] It is also needed in order to confirm theoretical data which predicts N and NH abundances in stars which produce N and NH and other stars with left over trace amounts of N and NH.[9] Using current values for rotational constants and vibrations of NH as well as from OH and CH lets us study the CNO abundances without resorting to a full spectrum synthesis with a 3D model atmosphere.[10]

See also

References

This article was sourced from Creative Commons Attribution-ShareAlike License; additional terms may apply. World Heritage Encyclopedia content is assembled from numerous content providers, Open Access Publishing, and in compliance with The Fair Access to Science and Technology Research Act (FASTR), Wikimedia Foundation, Inc., Public Library of Science, The Encyclopedia of Life, Open Book Publishers (OBP), PubMed, U.S. National Library of Medicine, National Center for Biotechnology Information, U.S. National Library of Medicine, National Institutes of Health (NIH), U.S. Department of Health & Human Services, and USA.gov, which sources content from all federal, state, local, tribal, and territorial government publication portals (.gov, .mil, .edu). Funding for USA.gov and content contributors is made possible from the U.S. Congress, E-Government Act of 2002.
 
Crowd sourced content that is contributed to World Heritage Encyclopedia is peer reviewed and edited by our editorial staff to ensure quality scholarly research articles.
 
By using this site, you agree to the Terms of Use and Privacy Policy. World Heritage Encyclopedia™ is a registered trademark of the World Public Library Association, a non-profit organization.
 


Copyright © World Library Foundation. All rights reserved. eBooks from Project Gutenberg are sponsored by the World Library Foundation,
a 501c(4) Member's Support Non-Profit Organization, and is NOT affiliated with any governmental agency or department.