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Liesegang rings (geology)

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Liesegang rings (geology)

Typical Liesegang ring structures within cross-section

Liesegang rings () (also called Liesegangen rings or Liesegang bands) are colored bands of cement observed in sedimentary rocks that typically cut-across bedding.[1][2] These secondary (diagenetic) sedimentary structures exhibit bands of (authigenic) minerals that are arranged in a regular repeating pattern.[3] Liesegang rings are distinguishable from other sedimentary structures by their concentric or ring-like appearance. The precise mechanism from which Liesegang rings form is not entirely known and is still under research,[4] however there is a precipitation process that is thought to be the catalyst for Liesegang ring formation referred to as the Ostwald-Liesegang supersaturation-nucleation-depletion cycle.[5] Though Liesegang rings are considered a frequent occurrence in sedimentary rocks,[6] rings composed of iron oxide can also occur in permeable igneous and metamorphic rocks that have been chemically weathered.[7]

Contents

  • History 1
  • Mechanism for development 2
  • Occurrence in the environment 3
  • References 4

History

In 1896, a German Chemist named Raphael E. Liesegang first described Liesegang banding in his observations from the results of an experiment, although it is important to mention that Wilhelm Ostwald provided the earliest explanation for the phenomenon.[8] The purpose of Liesegang's experiment was to observe precipitate formation resulting from the chemical reaction produced when a drop of silver nitrate solution was placed onto the surface of potassium dichromate gel. The resultant precipitate of silver dichromate formed a concentric pattern of rings. Liesegang and successive other workers observed the behavior of precipitates forming rings in sedimentary rocks, hence these features became known as Liesegang rings.[3]

Mechanism for development

Anvil rock, Shawnee National Forest, IL

The process by which Liesegang rings develop is not completely understood.[4] Liesegang rings may form from the chemical segregation of iron oxides and other minerals during weathering.[2] One popular mechanism suggested by geochemists is that Liesegang rings develop when there is a lack of convection (advection) and has to do with the interdiffusion of reacting species such as oxygen and ferrous iron that precipitate in separate discrete bands which become spaced apart in a geometric pattern.[8] A process of precipitation known as the Ostwald-Liesegang supersaturation-nucleation-depletion cycle is known by the geologic community as a probable mechanism for Liesegang ring formation in sedimentary rocks.[5] In this process the "...diffusion of reactants leads to supersaturation and nucleation; this precipitation results in localized band formation and depletion of reactants in adjacent zones."[5] As Ostwald suggests, and in simpler terms - there is a localized formation of crystal seeds that occurs when the right level of supersaturation is reached, and once the crystal seeds form, the growth of the crystals is believed to lower the supersaturation level of fluids in pore spaces surrounding the crystals, thus mineralization that occurs after the initial crystal growth in the surrounding areas develops in bands or rings.[8] One classic example based on the Ostwald-Liesegang hypothesis is observed in water and rock interactions where iron hydroxide precipitates in sandstone through pore space.[8]

Occurrence in the environment

perspective
closeup
Liesegang ring present on a natural arch of sandstone, found at a beach near Khayelitsha, South Africa.
Liesegang Rings (concentric concretions) on east side of Saginaw Hill, Tucson Arizona

Liesegang ring patterns are considered to be

  1. ^ Jackson, Julia A., 1997. "Glossary of Geology." American Geological Institute, Alexandria, Virginia. 4th edition. P. 366
  2. ^ a b c Stow, A.V., 2009, Sedimentary rocks in the field. A color guide (3rd ed.), Pp. 103, 107.
  3. ^ a b c Middleton, Gerard V.; Church, Michael J.; Coniglio, Mario; Hardie, Lawrence A.; Longstaffe, Frederick J.; 2003. "Encyclopedia of Sediments and Sedimentary Rocks." Kluwer Academic Publishers, Dordrecht. Pp. 221, 224.
  4. ^ a b Krug, H.-J,. Brandtstadter, H., and Jacob, K.H., 1996. Morphological instabilities in pattern formation by precipitation and crystallization processes. Geologische Rundschau, 85: 19-28.
  5. ^ a b c Decelles, P.G., and Gutschick, R.C., 1983. Mississippian wood-grained chert and its significance in the western interior United States. Journal of Sedimentary Petrology, 53: 1175-1191.
  6. ^ a b Merino, E., 1984. Survey of geochemical self-patterning phenomena. In Nicolis, G., and Baras, F. (eds.), Chemical Instabilities. Dordrecht: D. Reidel Publishing Company, pp. 305-328.
  7. ^ a b c d e McBride, E. F. (2003), Pseudofaults resulting from compartmentalized Liesegang bands: update. Sedimentology, 50: 725–730. doi:10.1046/j.1365-3091.2003.00572.x
  8. ^ a b c d Steefel, Carl I., 2008, Geochemical Kinetics and Transport: in Brantley, Susan L; Kubicki, James d; White, Art F. (eds), Kinetics of Water-Rock Interaction, Springer New York, p. 545-589.
  9. ^ Fu, L., Milliken, K.L., and Sharp, J.M. Jr., 1994. Porosity and permeability variations in fractured and Liesegang-banded Breathitt sandstones (Middle Pennyslvanian), eastern Kentucky: diagenetic controls and implications for modeling dual-porosity systems. Journal of Hydrology, 154: 351-381.
  10. ^ Chen, W., Park, A., and Ortoleva, P., 1990. Diagenesis through coupled processes: modeling approach, self-organization, and implications for exploration. American Association of Petroleaum Geologists Memoir 49, Prediction of Quality Through Chemical Modeling. pp. 103-130.

References

[2] Liesegang rings can have the appearance of fine lamination and can be mistaken for laminae when parallel or subparallel to the bedding plane, and are more easily differentiated from laminae when the rings are observed cutting-across beds or lamination.[7] Pseudofaults are the result of Liesegang rings developing within areas of the rock that are adjacent to each other, but at varying stratigraphic levels.[7] offset is attributed to pseudofaulting.observed), Liesegang ring patterns can be misinterpreted for faults; the rings may appear to be "offset," however the laminae in the rock exhibit an unbroken pattern, therefore the calcisiltites such as carbonate siltstones (sedimentary rocks For instance, in certain types of [10]

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