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Monomers

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Monomers

A monomer, pronounced mŏn'ə-mər, or MON-uh-mer, (from Greek mono "one" and meros "part") is a molecule that may bind chemically to other molecules to form a polymer.[1][2] The term "monomeric protein" may also be used to describe one of the proteins making up a multiprotein complex. The most common natural monomer is glucose, which is linked by glycosidic bonds into polymers such as cellulose and starch, and is over 77% of the mass of all plant matter.[3] Most often the term monomer refers to the organic molecules which form synthetic polymers, such as, for example, vinyl chloride, which is used to produce the polymer polyvinyl chloride (PVC).The process by which monomers combine end to end to form a polymer is called polymerisation.

IUPAC definition

Monomer: A substance composed of monomer molecules.[4]

Monomer molecule: A molecule which can undergo polymerization, thereby
contributing constitutional units to the essential structure of a macromolecule.[4]

Natural monomers

Amino acids are natural monomers that polymerize at ribosomes to form proteins. Nucleotides, monomers found in the cell nucleus, polymerize to form nucleic acidsDNA and RNA. Glucose monomers can polymerize to form starches, glycogen or cellulose; xylose monomers can polymerise to form xylan. In all these cases, a hydrogen atom and a hydroxyl (-OH) group are lost to form H2O, and an oxygen atom links each monomer unit. Due to the formation of water as one of the products, these reactions are known as dehydration.

Isoprene is a natural monomer and polymerizes to form natural rubber, most often cis-1,4-polyisoprene, but also trans-1,4-polyisoprene.

Molecular weight

The lower molecular weight compounds built from monomers are also referred to as dimers, trimers, tetramers, pentamers, octamers, 20-mers, etc. if they have 2, 3, 4, 5, 8, or 20 monomer units, respectively.[5] Any number of these monomer units may be indicated by the appropriate Greek prefix; e.g. a decamer is formed from 10 monomers. Larger numbers are often stated in English or numbers instead of Greek. Molecules made of a small number of monomer units, up to a few dozen, are called oligomers.

Industrial use

Considering the current tight monomers market, particularly in propylene, and the benefits of membrane-based recovery processes, major polyolefin producers around the world already employ such recovery processes in new state-of-the-art plants. In order to enhance the competitiveness of older plants, the use of a recovery solution is becoming mandatory.[6]

See also

Notes

External links

  • Polymer Structurehu:Molekula#Monomer
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