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Plutonium-238

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Title: Plutonium-238  
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Subject: Nuclear fuel, Radioactive waste, Voyager 1, Neptunium, Common beta emitters
Collection: Actinides, Fertile Materials, Isotopes of Plutonium, Radioisotope Fuels
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Plutonium-238

Plutonium-238

Plutonium-238 oxide pellet glowing from its own heat

General
Name, symbol Plutonium-238,238Pu
Neutrons 144
Protons 94
Nuclide data
Half-life 87.7 years
Parent isotopes 242Cm (α)
238Np (β)
238Am (β+)
Decay products 234U
Isotope mass 238.049553 u
Spin 0
Decay mode Decay energy
Alpha decay 5.593 MeV

Plutonium-238 (also known as Pu-238 or 238Pu) is a radioactive isotope of plutonium that has a half-life of 87.7 years.

Plutonium-238 is a very powerful alpha emitter and – unlike other isotopes of plutonium – it does not emit significant amounts of other, more penetrating and thus more problematic radiation. This makes the plutonium-238 isotope suitable for usage in radioisotope thermoelectric generators (RTGs) and radioisotope heater units – one gram of plutonium-238 generates approximately 0.5 watts of thermal power.

Contents

  • History 1
  • Production 2
  • Applications 3
  • United States supply 4
  • See also 5
  • References 6
  • External links 7

History

Plutonium-238 was the first uranium-238 with deuterons, creating neptunium-238, which then decays to form plutonium-238. Plutonium-238 decays to uranium-234 and then further along the radium series to lead-206.

Production

Reactor-grade plutonium from spent nuclear fuel contains various isotopes of plutonium. Pu-238 makes up only one or two percent, but it may be responsible for much of the short-term decay heat because of its short half-life relative to other plutonium isotopes. Reactor-grade plutonium is not useful for producing Pu-238 for RTGs because difficult isotopic separation would be needed.

Pure plutonium-238 is prepared by irradiation of neptunium-237, one of the minor actinides that can be recovered from spent nuclear fuel during reprocessing, or by the irradiation of americium[1] in a reactor. In both cases, the targets are subjected to a chemical treatment, including dissolution in nitric acid to extract the plutonium-238. A 100 kg sample of light water reactor fuel that has been irradiated for three years contains only about 700 grams of neptunium-237, and the neptunium must be extracted selectively. Significant amounts of pure Pu-238 could also be produced in a thorium fuel cycle.[2]

Applications

The main application of Pu-238 is as the heat source in radioisotope thermoelectric generators (RTGs).

RTG technology was first developed by Los Alamos National Laboratory during the 1960s and 1970s to provide radioisotope thermoelectric generator power for cardiac pacemakers. Of the 250 plutonium-powered pacemakers Medtronic manufactured, twenty-two were still in service more than twenty-five years later, a feat that no battery-powered pacemaker could achieve.[3]

This same RTG power technology has been used in spacecraft such as Voyager 1 and 2, Cassini–Huygens and New Horizons, and in other devices, such as the Mars Science Laboratory, for long-term nuclear power generation.[4]

United States supply

The United States stopped producing bulk plutonium-238 in 1988;[5] since 1993, all of the plutonium-238 used in American spacecraft has been purchased from Russia. In total, 16.5 kilograms have been purchased but Russia is no longer producing plutonium-238 and their own supply is reportedly running low.[6][7]

In 2009, the U.S. Department of Energy (DOE) requested funding to restart American domestic production.[8][9] It is estimated that to restart production will cost between $75 million and $90 million over five years.[10] Since the DOE would be responsible for producing the plutonium-238 for NASA, the two agencies want to split the cost of restarting production.[10] Congress has given NASA some of the money requested, $10 million in 2011 and the same in 2012.[10] The U.S. Congress has denied the DOE's funding request for three years in a row.[10]

Between 3.3 pounds (1.5 kg) and 4.4 pounds (2.0 kg) would be produced per year to support NASA's robotic science missions, although if future human missions require plutonium-238 then even more would need to be produced.[10] The Advanced Test Reactor at the Idaho National Laboratory and the High Flux Isotope Reactor at the Oak Ridge National Laboratory are both seen as potential producers.[7] About 15 kg per GWyr could be created in liquid fluoride thorium reactors (LFTRs).

Jim Adams, deputy director of planetary science at NASA, said that there is enough of the fuel for NASA missions until around 2022. He says if NASA does not get more after that, "then we won't go beyond Mars anymore. We won't be exploring the solar system beyond Mars and the asteroid belt".[9] After production has been restarted it is predicted that it would take at least five years to get enough for a single spacecraft mission.[8] In February 2013, it was reported that a small amount of plutonium-238 was successfully produced by Oak Ridge's High Flux Isotope Reactor – this was the first time the United States had produced 238Pu since production ended in the late 1980s.[11] Jim Green, head of NASA's planetary science division, stated in March 2013 that NASA expects to receive reports back from DOE later in 2013 on a complete schedule that would put plutonium-238 on track to be produced at about 1.5 kg (3.3 lb) per year.[11][4]

See also

References

  1. ^ "Process for producing ultra-pure ... - Google Patents". Google.com. Retrieved 2011-09-19. 
  2. ^ http://www.thoriumenergyalliance.com/downloads/plutonium-238.pdf
  3. ^ Kathy DeLucas; Jim Foxx; Robert Nance (1st Quarter, 2005). "From heat sources to heart sources: Los Alamos made material for plutonium-powered pumper". Actinide Research Quarterly. Los Alamos National Laboratory. Retrieved 2012-01-23. 
  4. ^ a b Alexandra Witze, Pu to power its deep-space missions - but that will not get it very far.238Nuclear power: Desperately seeking plutonium, NASA has 35 kg of , Nature, 25 Nov 2014
  5. ^ Steven D. Howe, Douglas Crawford, Jorge Navarro, Terry Ring. "Economical Production of Pu - 238: Feasibility Study". Center for Space Nuclear Research. Retrieved 2013-03-19. 
  6. ^ "Commonly Asked Questions About Radioisotope Power Systems".  
  7. ^ a b "Plutonium-238 Production Project". Department of Energy. 5 February 2011. Retrieved 2 July 2012. 
  8. ^ a b "Plutonium Shortage Could Stall Space Exploration". NPR. Retrieved 2011-09-19. 
  9. ^ a b Greenfieldboyce, Nell. "The Plutonium Problem: Who Pays For Space Fuel?" NPR, 8 November 2011.
  10. ^ a b c d e Wall, Mike (6 April 2012). "Plutonium Production May Avert Spacecraft Fuel Shortage". Space.com. Retrieved 2 July 2012. 
  11. ^ a b Clark, Stephen (20 March 2013). "U.S. laboratory produces first plutonium in 25 years". Spaceflightnow. Retrieved 21 March 2013. 

External links

  • Story of Seaborg's discovery of Pu-238, especially pages 34-35.
  • NLM Hazardous Substances Databank – Plutonium, Radioactive
Lighter:
plutonium-237
Plutonium-238 is an
isotope of plutonium
Heavier:
plutonium-239
Decay product of:
curium-242 (α)
americium-238 (β+)
neptunium-238 (β-)
uranium-238 (β-β-)
Decay chain
of plutonium-238
Decays to:
uranium-234 (α)
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