World Library  
Flag as Inappropriate
Email this Article

Flash point

Article Id: WHEBN0000286681
Reproduction Date:

Title: Flash point  
Author: World Heritage Encyclopedia
Language: English
Subject: Jet fuel, Chembox/testcases3, Chembox/testcases2, Chembox/testcases7images, Fuel oil
Collection: Combustion, Threshold Temperatures
Publisher: World Heritage Encyclopedia

Flash point

Flaming cocktails with a flash point lower than room temperature.

The flash point of a volatile material is the lowest temperature at which it can vaporise to form an ignitable mixture in air. Measuring a flash point requires an ignition source. At the flash point, the vapor may cease to burn when the ignition source is removed.

The flash point is not to be confused with the autoignition temperature (which does not require an ignition source) or with the fire point (the temperature at which the vapor continues to burn after being ignited).

Neither the flash point nor the fire point is dependent on the temperature of the ignition source, which is much higher.


  • Liquids 1
  • Mechanism 2
  • Measurement 3
  • Examples 4
  • Standardization 5
  • See also 6
  • References 7


The flash point is a descriptive characteristic that is used to distinguish flammable liquids (such as petrol) from combustible liquids.

It is also used to characterize the fire hazards of liquids. Liquids which have a flash point less than 37.8 or 60.5 °C (100.0 or 140.9 °F), depending on the standard that is used, are called flammable — whereas liquids having a flash point above that temperature are called combustible.[1]


Every liquid has a vapor pressure, which is a function of that liquid's temperature. As the temperature increases, the vapor pressure increases. As the vapor pressure increases, the concentration of vapor of the flammable liquid in the air increases. Hence, temperature determines the concentration of vapor of the flammable liquid in the air.

A certain concentration of vapor in the air is necessary to sustain combustion, and that concentration is different for each flammable liquid. The flash point of a flammable liquid is the lowest temperature at which there will be enough flammable vapor to ignite when an ignition source is applied.


Automatic flash point tester according to Pensky-Martens closed cup method with an integrated fire extinguisher.

There are two basic types of flash point measurement: open cup and closed cup.

In open cup devices the sample is contained in an open cup which is heated, and at intervals a flame is brought over the surface. The measured flash point will actually vary with the height of the flame above the liquid surface, and at sufficient height the measured flash point temperature will coincide with the fire point. The best known example is the Cleveland open cup (COC).

There are two types of closed cup testers: non-equilibrium, such as Pensky-Martens where the vapors above the liquid are not in temperature equilibrium with the liquid, and equilibrium, such as Small Scale (commonly known as Setaflash) where the vapors are deemed to be in temperature equilibrium with the liquid. In both these types the cups are sealed with a lid through which the ignition source can be introduced. Closed cup testers normally give lower values for the flash point than open cup (typically 5–10 °C or 9–18 °F lower) and are a better approximation to the temperature at which the vapor pressure reaches the lower flammable limit.

The flash point is an empirical measurement rather than a fundamental physical parameter. The measured value will vary with equipment and test protocol variations, including temperature ramp rate (in automated testers), time allowed for the sample to equilibrate, sample volume and whether the sample is stirred.

Methods for determining the flash point of a liquid are specified in many standards. For example, testing by the Pensky-Martens closed cup method is detailed in ASTM D93, IP34, ISO 2719, DIN 51758, JIS K2265 and AFNOR M07-019. Determination of flash point by the Small Scale closed cup method is detailed in ASTM D3828 and D3278, EN ISO 3679 and 3680, and IP 523 and 524.

CEN/TR 15138 Guide to Flash Point Testing and ISO TR 29662 Guidance for Flash Point Testing cover the key aspects of flash point testing.


Fuel Flash point Autoignition
Ethanol (70%) 16.6 °C (61.9 °F)[2] 363 °C (685 °F)[2]
Gasoline (petrol) −43 °C (−45 °F)[3] 280 °C (536 °F)[4]
Diesel (2-D) >52 °C (126 °F)[3] 256 °C (493 °F)[4]
Jet fuel (A/A-1) >38 °C (100 °F) 210 °C (410 °F)
Kerosene >38–72 °C (100–162 °F) 220 °C (428 °F)
Vegetable oil (canola) 327 °C (621 °F)
Biodiesel >130 °C (266 °F)

Gasoline (petrol) is a fuel for use in a spark-ignition engine. The fuel is mixed with air within its flammable limits and heated above its flash point, then ignited by the spark plug. To ignite, the fuel must have a low flash point, but in order to avoid preignition caused by residual heat in a hot combustion chamber, the fuel must have a high autoignition temperature.

Diesel fuel flash points vary between  52 and 96 °C (126 and 205 °F). Diesel is suitable for use in a compression-ignition engine. Air is compressed until it has been heated above the autoignition temperature of the fuel, which is then injected as a high-pressure spray, keeping the fuel-air mix within flammable limits. In a diesel-fueled engine, there is no ignition source (such as the spark plugs in a gasoline engine). Consequently, diesel fuel must have a high flash point and a low autoignition temperature.

Jet fuel flash points also vary with the composition of the fuel. Both Jet A and Jet A-1 have flash points between 38 and 66 °C (100 and 151 °F), close to that of off-the-shelf kerosene. Yet both Jet B and JP-4 have flash points between −23 and −1 °C (−9 and 30 °F).


Automatic Pensky-Martens closed cup tester with an integrated fire extinguisher

Flash points of substances are measured according to standard test methods. These test methods define the apparatus required to carry out the measurement, key test parameters, the procedure for the operator or automated apparatus to follow, and the precision of the test method.

Standard test methods are written and controlled by a number of national and international committees and organizations. The three main bodies are the CEN / ISO Joint Working Group on Flash Point (JWG-FP), ASTM D02.8B Flammability Section and the Energy Institute's TMS SC-B-4 Flammability Panel.

See also


  1. ^ NFPA 30: Flammable and Combustible Liquids Code, 2012 Edition Retrieved January 4, 2014.
  2. ^ a b "Ethanol MSDS" (PDF). Retrieved January 4, 2014. 
  3. ^ a b "Flash Point — Fuels". Retrieved January 4, 2014. 
  4. ^ a b "Fuels and Chemicals — Autoignition Temperatures". Retrieved January 4, 2014. 
This article was sourced from Creative Commons Attribution-ShareAlike License; additional terms may apply. World Heritage Encyclopedia content is assembled from numerous content providers, Open Access Publishing, and in compliance with The Fair Access to Science and Technology Research Act (FASTR), Wikimedia Foundation, Inc., Public Library of Science, The Encyclopedia of Life, Open Book Publishers (OBP), PubMed, U.S. National Library of Medicine, National Center for Biotechnology Information, U.S. National Library of Medicine, National Institutes of Health (NIH), U.S. Department of Health & Human Services, and, which sources content from all federal, state, local, tribal, and territorial government publication portals (.gov, .mil, .edu). Funding for and content contributors is made possible from the U.S. Congress, E-Government Act of 2002.
Crowd sourced content that is contributed to World Heritage Encyclopedia is peer reviewed and edited by our editorial staff to ensure quality scholarly research articles.
By using this site, you agree to the Terms of Use and Privacy Policy. World Heritage Encyclopedia™ is a registered trademark of the World Public Library Association, a non-profit organization.

Copyright © World Library Foundation. All rights reserved. eBooks from Project Gutenberg are sponsored by the World Library Foundation,
a 501c(4) Member's Support Non-Profit Organization, and is NOT affiliated with any governmental agency or department.