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Copper(II) nitrate

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Title: Copper(II) nitrate  
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Subject: Nitrates, Copper chromite, Nickel(II) nitrate, Copper(I) oxide, Nitric acid
Collection: Copper Compounds, Nitrates, Oxidizing Agents, Pyrotechnic Colorants, Pyrotechnic Oxidizers
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Copper(II) nitrate

Copper(II) nitrate
Names
IUPAC name
Copper(II) nitrate
Other names
Cupric nitrate
Identifiers
 Y
(trihydrate) N
(hexahydrate) N
(hemipentahydrate) N
ChEBI  N
ChemSpider  Y
Jmol-3D images Image
PubChem
RTECS number GL7875000
UNII  Y
Properties
Cu(NO3)2
Molar mass 187.5558 g/mol (anhydrous)
241.60 g/mol (trihydrate)
232.591 g/mol (hemipentahydrate)
Appearance blue crystals
hygroscopic
Density 3.05 g/cm3 (anhydrous)
2.32 g/cm3 (trihydrate)
2.07 g/cm3 (hexahydrate)
Melting point 256 °C (493 °F; 529 K) (anhydrous, decomposes)
114.5 °C (trihydrate)
26.4 °C (hexahydrate, decomposes)
Boiling point 170 °C (338 °F; 443 K) (trihydrate, decomposes)
trihydrate:[1]
381 g/100 mL (40 °C)
666 g/100 mL (80 °C)
hexahydrate:[1]
243.7 g/100 mL (80 °C)
Solubility hydrates very soluble in ethanol, ammonia, water; insoluble in ethyl acetate
Structure
orthorhombic (anhydrous)
rhombohedral (hydrates)
Hazards
Main hazards Irritant, Oxidizer
Safety data sheet O2·3H2)3Cu(NO
NFPA 704
0
1
1
OX
US health exposure limits (NIOSH):
PEL (Permissible)
TWA 1 mg/m3 (as Cu)[2]
REL (Recommended)
TWA 1 mg/m3 (as Cu)[2]
TWA 100 mg/m3 (as Cu)[2]
Related compounds
Other anions
Copper(II) sulfate
Copper(II) chloride
Other cations
Nickel(II) nitrate
Zinc nitrate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
 N  (: Y/N?)

Copper(II) nitrate, crystalline solid. Anhydrous copper nitrate forms deep blue-green crystals and sublimes in a vacuum at 150-200 °C.[3] Copper nitrate also occurs as five different hydrates, the most common ones being the trihydrate and hexahydrate. These materials are more commonly encountered in commerce than in the laboratory.

Contents

  • Synthesis and reactions 1
  • Structure 2
    • Anhydrous copper(II) nitrate 2.1
    • Hydrated copper(II) nitrate 2.2
  • Applications 3
    • Organic Synthesis 3.1
  • References 4
  • External links 5

Synthesis and reactions

Aqueous solution of copper(II) nitrate.

Hydrated copper nitrate can be prepared by hydration of the anhydrous material or by treating copper metal with an aqueous solution of silver nitrate or concentrated nitric acid:[4]

Cu + 4 HNO3 → Cu(NO3)2 + 2 H2O + 2 NO2

Anhydrous Cu(NO3)2 forms when copper metal is treated with N2O4:

Cu + 2 N2O4 → Cu(NO3)2 + 2 NO

Attempted dehydration of any of the hydrated copper(II) nitrates by heating instead affords the oxides, not Cu(NO3)2. At 80 °C, the hydrates convert to "basic copper nitrate" (Cu2(NO3)(OH)3), which converts to CuO at 180 °C.[4] Exploiting this reactivity, copper nitrate can be used to generate nitric acid by heating it until decomposition and passing the fumes directly into water. This method is similar to the last step in the Ostwald process. The equations are as follows:

2 Cu(NO3)2 → 2 CuO + 4 NO2 + O2
3NO2 + H2O → 2HNO3 + NO

Structure

Anhydrous copper(II) nitrate

Anhydrous copper(II) nitrate has been crystallized in two solvate-free polymorphs.[5][6] α- and β-Cu(NO3)2 are fully 3D coordination polymer networks. The alpha form has only one Cu environment, with [4+1] coordination, but the beta form has two different copper centers, one with [4+1] and one that is square planar. The nitromethane solvate also features "[4+ 1] coordination", with four short Cu-O bonds of approximately 200 pm and one longer bond at 240 pm.[7] They are coordination polymers, with infinite chains of copper(II) centers and nitrate groups. In the gas phase, copper(II) nitrate features two bidentate nitrate ligands (see image at upper right).[8] Thus, evaporation of the solid entails "cracking" to give the copper(II) nitrate molecule.

Hydrated copper(II) nitrate

Five hydrates have been reported: the monohydrate (Cu(NO3)2·H2O),[6] the sesquihydrate (Cu(NO3)2·1.5H2O),[9] the hemipentahydrate (Cu(NO3)2·2.5H2O),[10] a trihydrate (Cu(NO3)2·3H2O),[11] and a hexahydrate (Cu(H2O)6](NO3)2).[12] The hexahydrate is interesting because the Cu-O distances are all equal, not revealing the usual effect of Jahn-Teller distortion that is otherwise characteristic of octahedral Cu(II) complexes. This non-effect is attributed to the strong hydrogen bonding that limits the elasticity of the Cu-O bonds.

Applications

Copper(II) nitrate finds a variety of applications, the main one being its conversion to pyrotechnics.[4] It is often used in school laboratories to demonstrate chemical voltaic cell reactions.

Organic Synthesis

Copper nitrate, in combination with acetic anhydride, is an effective reagent for nitration of aromatic compounds, under what are known as "Menke conditions", in honor of the Dutch chemist who discovered that metal nitrates are effective reagents for nitration.[13] Hydrated copper nitrate absorbed onto clay affords a reagent called "Claycop". The resulting blue-colored clay is used as a slurry, for example for the oxidation of thiols to disulfides. Claycop is also used to convert dithioacetals to carbonyls.[14] A related reagent based on montmorillonite has proven useful for the nitration of aromatic compounds.[15]

References

  1. ^ a b Perrys' Chem Eng Handbook, 7th Ed
  2. ^ a b c "NIOSH Pocket Guide to Chemical Hazards #0150".  
  3. ^ Pass and Sutcliffe (1968). Practical Inorganic Chemistry. London: Chapman and Hall. 
  4. ^ a b c H.Wayne Richardson "Copper Compounds" Ullmann's Encyclopedia of Industrial Chemistry 2005, Wiley-VCH, Weinheim. doi:10.1002/14356007.a07 567.
  5. ^ α-Cu(NO3)2S. C. Wallwork, W. E. Addison, "The crystal structures of anhydrous nitrates and their complexes. Part I. The α form of copper(II) nitrate" J. Chem. Soc. (1965) 2925-2933. doi:10.1039/JR9650002925.
  6. ^ a b β-Cu(NO3)2: S. I. Troyanov, I. V. Morozov, K. O. Znamenkov, Yu. M. Korenev, "Synthesis and X-Ray Structure of New Copper(II) Nitrates: Cu(NO3)2·H2O and β-modification of Cu(NO3)2" Z. Anorg. Allg. Chem. (1995) vol. 621, pp. 1261–1265. doi:10.1002/zaac.19956210727
  7. ^ B. Duffin and S. C. Wallwork "The crystal structure of anhydrous nitrates and their complexes. II. The 1:1 copper(II) nitrate-nitromethane complex" Acta Crystallographica 1966. volume 20, pp. 210-213. doi:10.1107/S0365110X66000434
  8. ^ R. E. LaVilla, S. H. Bauer "The Structure of Gaseous Copper(II) Nitrate as Determined by Electron Diffraction" J. Am. Chem. Soc., 1963, volume 85, pp 3597–3600. doi:10.1021/ja00905a015
  9. ^ K. Dornberger-Schiff, J. Leciejewicz, "Zur Struktur des Kupfernitrates Cu(NO3)2.1.5H2O" Acta Cryst. 1958, volume 11, pp. 825–826. doi:10.1107/S0365110X58002322
  10. ^ B. Morosin, "The crystal structure of Cu(NO3)2.2.5H2O" Acta Cryst. 1970, volume B26, pp. 1203–1208. doi:10.1107/S0567740870003898
  11. ^ J. Garaj, Sbornik Prac. Chem.-Technol. Fak. Svst., Cskosl. 1966, pp. 35–39.
  12. ^ R. Zibaseresht, R. M. Hartshorn,"Hexaaquacopper(II) dinitrate: absence of Jahn-Teller distortion" Acta Cryst. 2006, volume E62, pp. i19–i22. doi:10.1107/S1600536805041851
  13. ^ Menke J.B. (1925). "Nitration with nitrates". Recueil des Travaux Chimiques des Pays-Bas 44: 141.  
  14. ^ Balogh, M. "Copper(II) Nitrate–K10 Bentonite Clay" in Encyclopedia of Reagents for Organic Synthesis (Ed: L. Paquette) 2004, J. Wiley & Sons, New York. doi:10.1002/047084289.
  15. ^ Collet, C.; Delville, A.; Laszlo, P. "Clays Direct Aromatic Nitration" Angewandte Chemie International Edition in English, 2003, Volume 29, Issue 5 , Pages 535–536. doi:10.1002/anie.199005351.

External links

  • National Pollutant Inventory – Copper and compounds fact sheet
  • ICSC Copper and compounds fact sheet
Salts and covalent derivatives of the Nitrate ion
HNO3 He
LiNO3 Be(NO3)2 B(NO3)4 C N O FNO3 Ne
NaNO3 Mg(NO3)2 Al(NO3)3 Si P S ClONO2 Ar
KNO3 Ca(NO3)2 Sc(NO3)3 Ti(NO3)4 VO(NO3)3 Cr(NO3)3 Mn(NO3)2 Fe(NO3)3 Co(NO3)2,
Co(NO3)3
Ni(NO3)2 Cu(NO3)2 Zn(NO3)2 Ga(NO3)3 Ge As Se Br Kr
RbNO3 Sr(NO3)2 Y Zr(NO3)4 Nb Mo Tc Ru Rh Pd(NO3)2 AgNO3 Cd(NO3)2 In Sn Sb Te I Xe
CsNO3 Ba(NO3)2   Hf Ta W Re Os Ir Pt Au Hg2(NO3)2,
Hg(NO3)2
Tl(NO3)3 Pb(NO3)2 Bi(NO3)3 Po At Rn
Fr Ra   Rf Db Sg Bh Hs Mt Ds Rg Cn Uut Fl Uup Lv Uus Uuo
La Ce(NO3)3,
Ce(NO3)4
Pr Nd Pm Sm Eu Gd(NO3)3 Tb Dy Ho Er Tm Yb Lu
Ac Th Pa UO2(NO3)2 Np Pu Am Cm Bk Cf Es Fm Md No Lr
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