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# Ginzburg-Landau theory

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 Title: Ginzburg-Landau theory Author: World Heritage Encyclopedia Language: English Subject: Collection: Publisher: World Heritage Encyclopedia Publication Date:

### Ginzburg-Landau theory

In physics, Ginzburg–Landau theory, named after Vitaly Lazarevich Ginzburg and Lev Landau, is a mathematical theory used to describe superconductivity. In its initial form, it was postulated as a phenomenological model which could describe type-I superconductors without examining their microscopic properties. Later, a version of Ginzburg–Landau theory was derived from the Bardeen-Cooper-Schrieffer microscopic theory by Lev Gor'kov, thus showing that it also appears in some limit of microscopic theory and giving microscopic interpretation of all its parameters.

## Introduction

Based on Landau's previously-established theory of second-order phase transitions, Ginzburg and Landau argued that the free energy, F, of a superconductor near the superconducting transition can be expressed in terms of a complex order parameter field, ψ, which is nonzero below a phase transition into a superconducting state and is related to the density of the superconducting component, although no direct interpretation of this parameter was given in the original paper. Assuming smallness of |ψ| and smallness of its gradients, the free energy has the form of a field theory.

$F = F_n + \alpha |\psi|^2 + \frac\left\{\beta\right\}\left\{2\right\} |\psi|^4 + \frac\left\{1\right\}\left\{2m\right\} \left| \left\left(-i\hbar\nabla - 2e\mathbf\left\{A\right\} \right\right) \psi \right|^2 + \frac\left\{|\mathbf\left\{B\right\}|^2\right\}\left\{2\mu_0\right\}$

where Fn is the free energy in the normal phase, α and β in the initial argument were treated as phenomenological parameters, m is an effective mass, e is the charge of an electron, A is the magnetic vector potential, and $\mathbf\left\{B\right\}=\nabla \times \mathbf\left\{A\right\}$ (B=curl(A)) is the magnetic field. By minimizing the free energy with respect to fluctuations in the order parameter and the vector potential, one arrives at the Ginzburg–Landau equations

$\alpha \psi + \beta |\psi|^2 \psi + \frac\left\{1\right\}\left\{2m\right\} \left\left(-i\hbar\nabla - 2e\mathbf\left\{A\right\} \right\right)^2 \psi = 0$
$\mathbf\left\{j\right\} = \frac\left\{2e\right\}\left\{m\right\} \mathrm\left\{Re\right\} \left\\left\{ \psi^* \left\left(-i\hbar\nabla - 2e \mathbf\left\{A\right\} \right\right) \psi \right\\right\}$

where j denotes the dissipation-less electrical current density and Re the real part. The first equation — which bears some similarities to the time-independent Schrödinger equation, but is principally different due to a nonlinear term — determines the order parameter, ψ. The second equation then provides the superconducting current.

## Simple interpretation

Consider a homogeneous superconductor where there is no superconducting current and the equation for ψ simplifies to:

$\alpha \psi + \beta |\psi|^2 \psi = 0. \,$

This equation has a trivial solution: ψ = 0. This corresponds to the normal state of the superconductor, that is for temperatures, above the superconducting transition temperature, T>Tc.

Below the superconducting transition temperature, the above equation is expected to have a non-trivial solution (that is ψ ≠ 0). Under this assumption the equation above can be rearranged into:

$|\psi|^2 = - \frac\left\{\alpha\right\} \left\{\beta\right\}.$

When the right hand side of this equation is positive, there is a nonzero solution for ψ (remember that the magnitude of a complex number can be positive or zero). This can be achieved by assuming the following temperature dependence of α: α(T) = α0 (T - Tc) with α0 / β > 0:

• Above the superconducting transition temperature, T > Tc, the expression α(T) / β is positive and the right hand side of the equation above is negative. The magnitude of a complex number must be a non-negative number, so only ψ = 0 solves the Ginzburg–Landau equation.
• Below the superconducting transition temperature, T < Tc, the right hand side of the equation above is positive and there is a non-trivial solution for ψ. Furthermore
$|\psi|^2 = - \frac\left\{\alpha_\left\{0\right\} \left(T - T_\left\{c\right\}\right)\right\} \left\{\beta\right\},$

that is ψ approaches zero as T gets closer to Tc from below. Such a behaviour is typical for a second order phase transition.

In Ginzburg–Landau theory the electrons that contribute to superconductivity were proposed to form a superfluid. In this interpretation, |ψ|2 indicates the fraction of electrons that has condensed into a superfluid.

## Coherence length and penetration depth

The Ginzburg–Landau equations predicted two new characteristic lengths in a superconductor which was termed coherence length, ξ. For T > Tc (normal phase), it is given by

$\xi = \sqrt\left\{\frac\left\{\hbar^2\right\}\left\{2 m |\alpha|\right\}\right\}.$

while for T < Tc (superconducting phase), where it is more relevant, it is given by

$\xi = \sqrt\left\{\frac\left\{\hbar^2\right\}\left\{4 m |\alpha|\right\}\right\}.$

It sets the exponential law according to which small perturbations of density of superconducting electrons recover their equilibrium value ψ0. Thus this theory proposed it characterized all superconductors by two length scales. The second one is the penetration depth, λ. It was previously introduced by the London brothers in their London theory. Expressed in terms of the parameters of Ginzburg-Landau model it is

$\lambda = \sqrt\left\{\frac\left\{m\right\}\left\{4 \mu_0 e^2 \psi_0^2\right\}\right\},$

where ψ0 is the equilibrium value of the order parameter in the absence of an electromagnetic field. The penetration depth sets the exponential law according to which an external magnetic field decays inside the superconductor.

The ratio κ = λ/ξ is known as the Ginzburg–Landau parameter. It has been shown that Type I superconductors are those with 0 < κ < 1/√2, and Type II superconductors those with κ > 1/√2.

The exponential decay of the magnetic field is equivalent with the Higgs mechanism in high-energy physics.

## Fluctuations in the Ginzburg-Landau model

Taking into account fluctuations. For Type II superconductors, the phase transition from the normal state is of second order, as demonstrated by Dasgupta and Halperin. While for Type I superconductors it is of first order as demonstrated by Halperin, Lubensky and Ma.

## Classification of superconductors based on Ginzburg-Landau theory

In the original paper Ginzburg and Landau observed the existence of two types of superconductors depending on the energy of the interface between the normal and superconducting states. The most important finding from Ginzburg–Landau theory was made by Alexei Abrikosov in 1957. He used Ginzburg–Landau theory to explain experiments on superconducting alloys and thin films. He found that in a type-II superconductor in a high magnetic field – the field penetrates in the form of hexagonal lattice of quantized tubes of flux.

In