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Osmotic

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Osmotic

For other uses, see Osmosis (disambiguation).

Osmosis is the spontaneous net movement of solvent molecules through a partially permeable membrane into a region of higher solute concentration, in the direction that tends to equalize the solute concentrations on the two sides.[1][2][3] It may also be used to describe a physical process in which any solvent moves, without input of energy,[4] across a semipermeable membrane (permeable to the solvent, but not the solute) separating two solutions of different concentrations.[5] Although osmosis does not require input of energy, it does use kinetic energy [6] and can be made to do work.[7]


The osmotic pressure is defined to be the pressure required to maintain an equilibrium, with no net movement of solvent. Osmotic pressure is a colligative property, meaning that the osmotic pressure depends on the molar concentration of the solute but not on its identity.

Osmosis is an essential aspect in biological systems, as biological membranes are semipermeable. In general, these membranes are impermeable to large and polar molecules, such as ions, proteins, and polysaccharides, while being permeable to non-polar and/or hydrophobic molecules like lipids as well as to small molecules like oxygen, carbon dioxide, nitrogen, nitric oxide, etc. Permeability depends on solubility, charge, or chemistry, as well as solute size. Water molecules travel through the plasma membrane, tonoplast membrane (vacuole) or protoplast by diffusing across the phospholipid bilayer via aquaporins (small transmembrane proteins similar to those in facilitated diffusion and in creating ion channels). Osmosis provides the primary means by which water is transported into and out of cells. The turgor pressure of a cell is largely maintained by osmosis, across the cell membrane, between the cell interior and its relatively hypotonic environment.[8]

Jean-Antoine Nollet first documented observation of osmosis in 1748.[9] The word "osmosis" descends from the words "endosmose" and "exosmose", which were coined by French physician René Joachim Henri Dutrochet (1776–1847) from the Greek words ένδον (endon : within), έξο (exo : outside), and ωσμος (osmos : push, impulsion).[10]

Basic explanations

Osmosis is a type of diffusion. Osmosis can occur when there is a partially permeable membrane, such as a cell membrane. When a cell is submerged in water, the water molecules pass through the cell membrane from an area of low solute concentration to high solute concentration (e.g. if the cell is submerged in saltwater, water molecules move out; if it is submerged in freshwater, however, water molecules move in); this is called osmosis. The cell membrane is selectively permeable, so only necessary materials are let into the cell and wastes are left out.[8] The word 'osmosis' is particular to the diffusion of water molecules into the cell.-


When the membrane has a volume of pure water on both sides, water molecules pass in and out in each direction at exactly the same rate; there is no net flow of water through the membrane.

Osmosis can be explained using the concept of thermodynamic free energy: the less concentrated solution contains more free energy, so its solvent molecules will tend to diffuse to a place of lower free energy in order to equalize free energy. Since the semipermeable membrane only allows solvent molecules to pass through it, the result is a net flow of water to the side with the more concentrated solution. Assuming the membrane does not break, this net flow will slow and finally stop as the pressure on the more concentrated side lessens and the movement in each direction becomes equal: this state is called dynamic equilibrium.

Osmosis can also be explained using the notion of entropy, from statistical mechanics. A system that has two solutions of different concentrations separated by a semipermeable membrane has less entropy than a similar system having two solutions of equal concentration. The system with the differing concentrations is said to be more ordered, and thus has less entropy. The second law of thermodynamics requires the presence of an osmotic flow that will take the system from an ordered state of low entropy to a disordered state of higher entropy. Thermodynamic equilibrium is achieved when the entropy gradient between the two solutions becomes zero.

Particle size has no bearing on osmotic pressure; this is the fundamental postulate of colligative properties.[11]



Osmotic pressure is the main cause of support in many plants. The osmotic entry of water raises the turgor pressure exerted against the cell wall, until it equals the osmotic pressure, creating a steady state.-

When a plant cell is placed in a hypertonic solution, the water in the cells moves to an area higher in solute concentration and the cell shrinks, and in doing so, becomes flaccid. This means the cell has become plasmolyzed – the cell membrane has completely left the cell wall due to lack of water pressure on it; the opposite of turgid.

Also, osmosis is responsible for the ability of plant roots to draw water from the soil. Since there are many fine roots, they have a large surface area, and water enters the roots by osmosis.

Osmosis can also be seen when potato slices are added to a high concentration of salt solution. The water from inside the potato moves to the salt solution, causing the potato to shrink and to lose its 'turgor pressure'. The more concentrated the salt solution, the bigger the difference in size and weight of the potato slice.

In unusual environments, osmosis can be very harmful to organisms. For example, freshwater and saltwater aquarium fish placed in water of a different salinity than that to which they are adapted to will die quickly, and in the case of saltwater fish, dramatically. Another example of a harmful osmotic effect is the use of table salt to kill leeches and slugs.

Suppose an animal or a plant cell is placed in a solution of sugar or salt in water.

  1. If the medium is hypotonic — a dilute solution, with a higher water concentration than the cell — the cell will gain water through osmosis.
  2. If the medium is isotonic — a solution with exactly the same water concentration as the cell — there will be no net movement of water across the cell membrane.
  3. If the medium is hypertonic — a concentrated solution, with a lower water concentration than the cell — the cell will lose water by osmosis.

Essentially, this means that if a cell is put in a solution which has a solute concentration higher than its own, then it will shrivel up, and if it is put in a solution with a lower solute concentration than its own, the cell will expand and burst. Electronucleal exchange is the passive diffusion of cations and anions across a semi-permeable membrane according to electrical charge.

Chemical gardens demonstrate the effect of osmosis in inorganic chemistry.

Factors

Osmotic pressure

Main article: Osmotic pressure

As mentioned before, osmosis may be opposed by increasing the pressure in the region of high solute concentration with respect to that in the low solute concentration region. The force per unit area, or pressure, required to prevent the passage of water through a selectively permeable membrane and into a solution of greater concentration is equivalent to the osmotic pressure of the solution, or turgor. Osmotic pressure is a colligative property, meaning that the property depends on the concentration of the solute, but not on its identity.

Osmotic gradient

The osmotic gradient is the difference in concentration between two solutions on either side of a semipermeable membrane, and is used to tell the difference in percentages of the concentration of a specific particle dissolved in a solution.

Usually the osmotic gradient is used while comparing solutions that have a semipermeable membrane between them allowing water to diffuse between the two solutions, toward the hypertonic solution (the solution with the higher concentration). Eventually, the force of the column of water on the hypertonic side of the semipermeable membrane will equal the force of diffusion on the hypotonic (the side with a lesser concentration) side, creating equilibrium. When equilibrium is reached, water continues to flow, but it flows both ways in equal amounts as well as force, therefore stabilizing the solution.

Variation

Reverse osmosis

Main article: Reverse osmosis

Reverse osmosis is a separation process that uses pressure to force a solvent through a semi-permeable membrane that retains the solute on one side and allows the pure solvent to pass to the other side.it is the process of forcing a solvent from a region of high solute concentration through a membrane to a region of low solute concentration by applying a pressure in excess of the osmotic pressure.

Forward osmosis

Main article: Forward osmosis

Osmosis may be used directly to achieve separation of water from a solution containing unwanted solutes. A "draw" solution of higher osmotic pressure than the feed solution is used to induce a net flow of water through a semi-permeable membrane, such that the feed solution becomes concentrated as the draw solution becomes dilute. The diluted draw solution may then be used directly (as with an ingestible solute like glucose), or sent to a secondary separation process for the removal of the draw solute. This secondary separation can be more efficient than a reverse osmosis process would be alone, depending on the draw solute used and the feedwater treated. Forward osmosis is an area of ongoing research, focusing on applications in desalination, water purification, water treatment, food processing, etc.

See also

References

  1. The intermediate word "osmose" and the word "osmotic" were coined by Scottish chemist p. 616.
  2. The word "osmosis" first appeared in: Jabez Hogg, The Microscope: Its History, Construction, and Application..., 6th ed. (London, England: George Routledge and Sons, 1867), p. 226.
  3. The etymology of the word "osmosis" is discussed in:

External links

  • Osmosis simulation in Java
  • NetLogo Osmosis simulation for educational use (Java Applet for fast PCs)
  • NetLogo Osmosis simulation for educational use (Java Applet, runs also on slow PCs)
  • An Osmosis Experiment

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