World Library  
Flag as Inappropriate
Email this Article

Principal quantum number

Article Id: WHEBN0000532481
Reproduction Date:

Title: Principal quantum number  
Author: World Heritage Encyclopedia
Language: English
Subject: Azimuthal quantum number, Energy level, Magnetic quantum number, Valence electron, Atomic orbital
Collection: Atomic Physics, Quantum Chemistry, Quantum Numbers
Publisher: World Heritage Encyclopedia

Principal quantum number

In quantum mechanics, the principal quantum number (symbolized n) is one of four quantum numbers which are assigned to each electron in an atom to describe that electron's state. As a discrete variable, the principal quantum number is always an integer. As n increases, the orbital becomes larger and the electron spends more time farther from the nucleus. As n increases, the electron is also at a higher potential energy and is therefore less tightly bound to the nucleus.

The principle quantum number was first created for use in the semiclassical Bohr model of the atom, distinguishing between different energy levels. With the development of modern quantum mechanics, the simple Bohr model was replaced with a more complex theory of atomic orbitals. However, modern theory still requires the principle quantum number. Apart from the principal quantum number, the other quantum numbers for bound electrons are the azimuthal quantum number, the magnetic quantum number, and the spin quantum number.

For an analogy, one could imagine a multistoried building with an elevator structure. The building has an integer number of floors, and a (well-functioning) elevator which can only stop at a particular floor. Furthermore, the elevator can only travel an integer number of levels. As with the principal quantum number, higher numbers are associated with higher potential energy.

Beyond this point the analogy breaks down; in the case of elevators the potential energy is gravitational but with the quantum number it is electromagnetic. The gains and losses in energy are approximate with the elevator, but precise with quantum state. The elevator ride from floor to floor is continuous whereas quantum transitions are discontinuous. Finally the constraints of elevator design are imposed by the requirements of architecture, but quantum behavior reflects fundamental laws of physics.


There are a set of quantum numbers associated with the energy states of the atom. The four quantum numbers n, , m, and s specify the complete and unique quantum state of a single electron in an atom, called its wave function or orbital. Two electrons belonging to the same atom can not have the same four quantum numbers, due to the Pauli exclusion principle. The wave function of the Schrödinger wave equation reduces to the three equations that when solved lead to the first three quantum numbers. Therefore, the equations for the first three quantum numbers are all interrelated. The principal quantum number arose in the solution of the radial part of the wave equation as shown below.

The Schrödinger wave equation describes energy eigenstates having corresponding real numbers En with a definite total energy which the value of En defines. The bound state energies of the electron in the hydrogen atom are given by:

E_n = \frac {E_1}{n^2} = \frac {-13.6\text{ eV}}{n^2}, \quad n=1,2,3,\ldots

The parameter n can take only positive integer values. The concept of energy levels and notation was utilized from the earlier Bohr model of the atom. Schrödinger's equation developed the idea from a flat two-dimensional Bohr atom to the three-dimensional wave function model.

In the Bohr model, the allowed orbits were derived from quantized (discrete) values of orbital angular momentum, L according to the equation

\mathbf{L} = n \cdot \hbar = n \cdot {h \over 2\pi}

where n = 1, 2, 3, … and is called the principal quantum number, and h is Planck's constant. This formula is not correct in quantum mechanics as the angular momentum magnitude is described by the azimuthal quantum number, but the energy levels are accurate and classically they correspond to the sum of potential and kinetic energy of the electron.

The principal quantum number n represents the relative overall energy of each orbital, and the energy of each orbital increases as the distance from the nucleus increases. The sets of orbitals with the same n value are often referred to as electron shells or energy levels.

The minimum energy exchanged during any wave-matter interaction is the wave frequency multiplied by Planck's constant. This causes the wave to display particle-like packets of energy called quanta. The difference between energy levels that have different n determine the Emission spectrum of the element.

In the notation of the periodic table, the main shells of electrons are labeled:

K (n = 1), L (n = 2), M (n = 3), etc.

based on the principal quantum number.

The principal quantum number is related to the radial quantum number, nr, by:

n = n_r + \ell + 1 \,

where is the azimuthal quantum number and nr is equal to the number of nodes in the radial wavefunction.

See also

External links

  • Periodic Table Applet: showing principal and azimuthal quantum number for each element
This article was sourced from Creative Commons Attribution-ShareAlike License; additional terms may apply. World Heritage Encyclopedia content is assembled from numerous content providers, Open Access Publishing, and in compliance with The Fair Access to Science and Technology Research Act (FASTR), Wikimedia Foundation, Inc., Public Library of Science, The Encyclopedia of Life, Open Book Publishers (OBP), PubMed, U.S. National Library of Medicine, National Center for Biotechnology Information, U.S. National Library of Medicine, National Institutes of Health (NIH), U.S. Department of Health & Human Services, and, which sources content from all federal, state, local, tribal, and territorial government publication portals (.gov, .mil, .edu). Funding for and content contributors is made possible from the U.S. Congress, E-Government Act of 2002.
Crowd sourced content that is contributed to World Heritage Encyclopedia is peer reviewed and edited by our editorial staff to ensure quality scholarly research articles.
By using this site, you agree to the Terms of Use and Privacy Policy. World Heritage Encyclopedia™ is a registered trademark of the World Public Library Association, a non-profit organization.

Copyright © World Library Foundation. All rights reserved. eBooks from Project Gutenberg are sponsored by the World Library Foundation,
a 501c(4) Member's Support Non-Profit Organization, and is NOT affiliated with any governmental agency or department.