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Rabi cycle

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Title: Rabi cycle  
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Subject: Neutral particle oscillation, Nitrogen-vacancy center, Rabi, Jaynes–Cummings model, Breit (disambiguation)
Collection: Atomic Physics, Quantum Optics
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Rabi cycle

In physics, the Rabi cycle (or Rabi flop) is the cyclic behaviour of a two-state quantum system in the presence of an oscillatory driving field. A great variety of physical processes belonging to the areas of quantum computing, condensed matter, atomic and molecular physics, and nuclear and particle physics can be conveniently studied in terms of two-level quantum mechanical systems, and exhibit Rabi flopping when coupled to an oscillatory driving field. The effect is important in quantum optics, magnetic resonance and quantum computing, and is named after Isidor Isaac Rabi.

A two-state system has two possible states, and if they are not degenerate (i.e. equal energy), the system can become "excited" when it absorbs a quantum of energy. When an atom (or some other two-level system) is illuminated by a coherent beam of photons, it will cyclically absorb photons and re-emit them by stimulated emission. One such cycle is called a Rabi cycle and the inverse of its duration the Rabi frequency of the photon beam. The effect can be modeled using the Jaynes-Cummings model and the Bloch vector formalism.


  • Mathematical treatment 1
  • How to prepare an oscillation experiment in a quantum system 2
  • Derivation of Rabi Formula in a Nonperturbative Procedure by means of the Pauli matrices 3
  • Rabi oscillation in Quantum computing 4
  • See also 5
  • References 6
  • External links 7

Mathematical treatment

A detailed mathematical description of the effect can be found on the page for the Rabi problem. For example, for a two-state atom (an atom in which an electron can either be in the excited or ground state) in an electromagnetic field with frequency tuned to the excitation energy, the probability of finding the atom in the excited state is found from the Bloch equations to be:

|c_b(t)|^2 \propto \sin^2 (\omega t/2) ,

where \omega is the Rabi frequency.

More generally, one can consider a system where the two levels under consideration are not energy eigenstates. Therefore, if the system is initialized in one of these levels, time evolution will make the population of each of the levels oscillate with some characteristic frequency, whose angular frequency[1] is also known as the Rabi frequency. The state of a two-state quantum system can be represented as vectors of a two-dimensional complex Hilbert space, which means every state vector \vert\psi\rangle is represented by two complex coordinates.

|\psi\rangle = \begin{pmatrix} c_1 \\ c_2\end{pmatrix} = c_1\begin{pmatrix} 1 \\ 0\end{pmatrix} + c_2\begin{pmatrix} 0 \\ 1\end{pmatrix} ; where c_1 and c_2 are the coordinates.[2]

If the vectors are normalized, c_1 and c_2 are related by {|c_1|}^2+{|c_2|}^2 = 1. The basis vectors will be represented as |1\rangle = \begin{pmatrix} 1 \\ 0\end{pmatrix} and |2\rangle = \begin{pmatrix} 0 \\ 1\end{pmatrix}

All observable physical quantities associated with this systems are 2 \times 2 Hermitian matrices, which means the Hamiltonian of the system is also a similar matrix.

How to prepare an oscillation experiment in a quantum system

One can construct an oscillation experiment consisting of following steps:[3]

(1) Prepare the system in a fixed state say |1\rangle

(2) Let the state evolve freely, under a Hamiltonian H for time t

(3) Find the probability P(t), that the state is in|1\rangle

If |1\ranglewas an eigenstate of H, P(t)=1 and there are no oscillations. Also if two states are degenerate, every state including |1\rangle is an eigenstate of H. As a result, there are no oscillations. So if H has no degenerate eigenstates, neither of which is |1\rangle, then there will be oscillations. The most general form of the Hamiltonian of a two-state system is given

\mathbf{H} = \begin{pmatrix} a_0+a_3 & a_1-ia_2\\ a_1+ia_2 & a_0-a_3\end{pmatrix}

here, a_0,a_1, a_2 and a_3 are real numbers. This matrix can be decomposed as,

\mathbf{H} = a_0\cdot\sigma_0 + a_1\cdot\sigma_1 + a_2\cdot\sigma_2 + a_3\cdot\sigma_3 ;

The matrix \sigma_0 is the 2 \times 2 identity matrix and the matrices \sigma_k (k = 1,2,3) are the Pauli matrices. This decomposition simplifies the analysis of the system especially in the time-independent case where the values of a_0,a_1,a_2and a_3are constants. Consider the case of a spin-1/2 particle in a magnetic field \mathbf{B} = B\mathbf{\hat z}. The interaction Hamiltonian for this system is

H=-\boldsymbol{\mu}\cdot\mathbf{B}=-\gamma\mathbf{S}\cdot\mathbf{B}=-\gamma\ S_z B.Where S_z = \frac{\hbar}{2} \sigma _3 = \frac{\hbar}{2} \begin{bmatrix}1&0\\ 0&-1 \end{bmatrix}

where \mu is the magnitude of the particle's magnetic moment,\gamma is Gyromagnetic ratio and \boldsymbol{\sigma} is the vector of Pauli matrices. Here eigenstates of Hamiltonian are eigenstates of \sigma_3 that is |1\rangle and |2\rangle. The probability that a system in the state |\psi\rang will be found to be in the arbitrary state |\phi\rangle is given by {|\langle\phi|\psi\rangle|}^2. Let system initially t=0 is in state |+X\rangle that is eigen state of \sigma_1 , |\psi(0)\rang= \frac{1}{\sqrt{2}}\begin{pmatrix} 1 \\ 1 \end{pmatrix}. That is |\psi(0)\rang= \frac{1}{\sqrt{2}}\begin{pmatrix} 1 \\ 0\end{pmatrix}+ \frac{1}{\sqrt{2}}\begin{pmatrix}0\\1\end{pmatrix}. Here Hamiltonian is time independent. So by solving time independent Schrödinger equation, we get state after time t is given by |\psi(t)\rang=e^{\frac{-iEt}{\hbar}}|\psi(0)\rang, where E is the total energy of system. So the state after time t is given by |\psi(t)\rang=e^{\frac{-iE_+t}{\hbar}}\frac{1}{\sqrt{2}}|1\rangle + e^{\frac{-iE_-t}{\hbar}}\frac{1}{\sqrt{2}}|2\rangle . Now suppose spin is measured in the x-direction at time t, the probability of finding spin-up is given by {|\langle\ +X|\psi(t)\rangle|}^2={|\frac{1}{\sqrt{2}} (\langle\ 1|+\langle\ 2|)(e^{\frac{-iE_+t}{\hbar}}\frac{1}{\sqrt{2}}|1\rangle +e^{\frac{-iE_-t}{\hbar}}\frac{1}{\sqrt{2}}|2\rangle)|}^2= {\cos}^2(\frac{\omega t}{2}) where \omega is a characteristic angular frequency given by \omega = \frac{E_- - E_+}{\hbar}=\gamma B where it has been assumed that E_- \geq E_+ .[4] So in this case probability of finding spin up state in X direction is oscillatory in time t when system is initially in Z direction. Similarly if we measure spin in Z direction then probability of finding \frac{\hbar}{2} of the system is \frac{1}{2}.In the case E_+ = E_- , that is when the Hamiltonian is degenerate there is no oscillation. So we can conclude that if the eigenstate of an above given Hamiltonian represents the state of a system, then probability of the system being that state is not oscillatory, but if we find probability of finding the system in other state, it is oscillatory. This is true for even time dependent Hamiltonian. For example H =-\gamma\ S_z B sin(\omega t), the probability that a measurement of system in Y direction at time t results in \frac{+\hbar}{2} is {|\langle\ +Y|\psi(t)\rangle|}^2={\cos}^2(\frac{\gamma B}{2\omega}\cos\omega t), where initial state is in |+Y\rangle .[5]

Derivation of Rabi Formula in a Nonperturbative Procedure by means of the Pauli matrices

Let us consider a Hamiltonian in the form \mathbf{H} = E_0\cdot\sigma_0 + W_1\cdot\sigma_1 + W_2\cdot\sigma_2 +\Delta\cdot\sigma_3= \begin{pmatrix} E_0+\Delta & W_1-iW_2\\ W_1+iW_2 & E_0-\Delta\end{pmatrix}.

The eigen values of this matrix are given by \lambda_+ =E_+=E_0+ \sqrt{\left\vert W \right\vert})^2=1.

Let \sin\theta=\frac{\left\vert W \right\vert}{\sqrt and \cos\theta=\frac{\Delta}{\sqrt. so \tan\theta=\frac{\left\vert W \right\vert}{\Delta}.

So we get {\left\vert a \right\vert}^2+{\left\vert a \right\vert}^2\frac{({1-\cos\theta})^2}{\sin^2\theta}=1. That is {\left\vert a \right\vert}^2=\cos^2\theta/2. Taking arbitrary phase angle \phi,we can write a=\exp(\imath\phi/2)\cos\theta/2. Similarly b=\exp(-\imath\phi/2)\sin\theta/2.

So eigen vector forE_+ eigen value is given by |E_+\rang=e^{\imath\phi/2}\begin{pmatrix}\cos\theta/2 \\e^{-\imath\phi}\sin\theta/2\end{pmatrix}.

As overall phase is immaterial so we can write |E_+\rang=\begin{pmatrix}\cos\theta/2 \\e^{-\imath\phi}\sin\theta/2\end{pmatrix}=\cos(\theta/2)|1\rang+e^{-\imath\phi}\sin(\theta/2)|2\rang.

Similarly we can find eigen vector for E_- value and we get |E_-\rang=-e^{\imath\phi}\sin(\theta/2)|1\rang+\cos(\theta/2)|2\rang.

From these two equations, we can write |1\rang=\cos(\theta/2)|E_+\rang-\sin(\theta/2)e^{-\imath\phi}|E_-\rang and |2\rang=e^{\imath\phi}\sin(\theta/2)|E_+\rang+\cos(\theta/2)|E_-\rang.

Let at time t=0, system be in |1\rang That Is |\psi(0)\rang=|1\rang=\cos(\theta/2)|E_+\rang-\sin(\theta/2)e^{-\imath\phi}|E_-\rang.

State of system after time t is given by |\psi(t)\rang=e^{\frac{-iEt}{\hbar}}|\psi(0)\rang=\cos(\theta/2)e^{\frac{-\imath E_+ t}{\hbar}}|E_+\rang-\sin(\theta/2)e^{-\imath\phi}e^{\frac{-\imath E_- t}{\hbar}}|E_-\rang.

Now a system is in one of the eigen states |1\rang or |2\rang, it will remain the same state, however in a general state as shown above the time evolution is non trivial.

The probability amplitude of finding the system at time t in the state |2\rang is given by |\langle\ 2|\psi(t)\rangle|=e^{-\imath\phi}\sin(\theta/2)\cos(\theta/2)(e^{\frac{-\imath E_+ t}{\hbar}}-e^{\frac{-\imath E_- t}{\hbar}}).

Now the probability that a system in the state |\psi(t)\rang will be found to be in the arbitrary state |2\rang is given by P_1\to_2(t)={|\langle\ 2|\psi(t)\rangle|}^2=e^{+\imath\phi}\sin(\theta/2)\cos(\theta/2)(e^{\frac{+\imath E_+ t}{\hbar}}-e^{\frac{+\imath E_t}{\hbar}})e^{-\imath\phi}\sin(\theta/2)\cos(\theta/2)(e^{\frac{-\imath E_+ t}{\hbar}}-e^{\frac{i\imath E_t}{\hbar}})=\frac{\sin^2\theta}{4}(2-2\cos(\frac{(E_+-E_-)t}{2\hbar}))

By simplifying P_1\to_2(t)=\sin^2(\theta)\sin^2(\frac{(E_+-E_-)t}{2\hbar})=\frac{\hbar}, which is simply unique Bohr frequency of the system and also called Rabi frequency. The formula(1) is known as Rabi formula. Now after time t the probability that the system in state |1\rang is given by{|\langle\ +X|\psi(t)\rangle|}^2=1-\sin^2(\theta)\sin^2(\frac{(E_+-E_-)t}{2\hbar}), which is also oscillatory. This type of oscillations between two levels are called Rabi oscillation and seen in many problems such as Neutrino oscillation, ionized Hydrogen molecule, Quantum computing, Ammonia maser etc.

Rabi oscillation in Quantum computing

Any two state quantum system can be used to model a qubit. Consider a Spin \frac{1}{2} system with magnetic moment \boldsymbol{\mu} placed in a classical magnetic field \boldsymbol{B}=B_0\hat{z}+B_1(\cos\omega t \hat{x}-\sin\omega t \hat{y}). Let \gamma be the gyromagnetic ratio for the system. The magnetic moment is thus \boldsymbol{\mu} = \frac{\hbar}{2} \gamma \boldsymbol{\sigma} . The Hamiltonian of this system is then given by \mathbf{H}=-\boldsymbol{\mu}\cdot\mathbf{B}= -\frac{\hbar}{2}\omega_0\sigma_z-\frac{\hbar}{2}\omega_1(\sigma_x\cos\omega t-\sigma_y\sin\omega t) where \omega_0=\gamma B_0 and \omega_1=\gamma B_1. One can find the eigenvalues and eigenvectors of this Hamiltonian by the above-mentioned procedure. Now, let the qubit be in state |1\rang at time t = 0 . Then, at time t , the probability of it being found in state |2\rang is given by P_{1\to2}(t)=\left(\frac{\omega_1}{\Omega}\right)^2\sin^2\left(\frac{\Omega t}{2}\right) where \Omega=\sqrt{(\omega-\omega_0)^2+\omega_1^2}. This phenomenon is called Rabi oscillation. Thus, the qubit oscillates between the |1\rang and |2\rang states. The maximum amplitude for oscillation is achieved at \omega=\omega_0, which is the condition for resonance. At resonance, the transition probability is given by P_{1\to2}(t)=\sin^2\left(\frac{\omega t}{2}\right). To go from state |1\rang to state |2\rang it is sufficient to adjust the time t during which the rotating field acts such that \frac{\omega_1 t}{2}=\frac{\pi}{2} or t=\frac{\pi}{\omega_1}. This is called a \pi pulse. If a time intermediate between 0 and \frac{\pi}{\omega_1} is chosen, we obtain a superposition of |1\rang and |2\rang. In particular for t=\frac{\pi}{2\omega_1}, we have a \frac{\pi}{2} pulse, which acts as: |1\rang \to \frac{|1\rang+|2\rang}{\sqrt{2}}. This operation has crucial importance in quantum computing. The equations are essentially identical in the case of a two level atom in the field of a laser when the generally well satisfied rotating wave approximation is made. Then \hbar\omega_0 is the energy difference between the two atomic levels, \omega is the frequency of laser wave and Rabi frequency \omega_1 is proportional to the product of the transition electric dipole moment of atom \vec{d}and electric field \vec{E} of the laser wave that is \omega_1\propto \vec{d}\cdot\vec{E}\hbar. In summary, Rabi oscillations are the basic process used to manipulate qubits. These oscillations are obtained by exposing qubits to periodic electric or magnetic fields during suitably adjusted time intervals.[6]

See also


  1. ^ Encyclopedia of Laser Physics and Technology - Rabi oscillations, Rabi frequency, stimulated emission
  2. ^ Griffiths, David (2005). Introduction to Quantum Mechanics (2nd ed.). p. 353. 
  3. ^ Sourendu Gupta (27 August 2013). "The physics of 2-state systems" (PDF). Tata Institute of Fundamental Research. 
  4. ^ Griffiths, David (2012). Introduction to Quantum Mechanics (2nd ed.) p. 191.
  5. ^ Griffiths, David (2012). Introduction to Quantum Mechanics (2nd ed.) p. 196 ISBN 978-8177582307
  6. ^ A Short Introduction to Quantum Information and Quantum Computation by Michel Le Bellac, ISBN 978-0521860567
  • Quantum Mechanics Volume 1 by C. Cohen-Tannoudji, Bernard Diu, Frank Laloe, ISBN 9780471164333
  • A Short Introduction to Quantum Information and Quantum Computation by Michel Le Bellac, ISBN 978-0521860567
  • The Feynman Lectures on Physics Vol 3 by Richard P. Feynman & R.B. Leighton, ISBN 978-8185015842
  • Modern Approach To Quantum Mechanics by John S Townsend, ISBN 9788130913148

External links

  • A Java applet that visualizes Rabi Cycles of two-state systems (laser driven)
  • extended version of the applet. Includes electron phonon interaction
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