Solid spherical harmonics

In physics and mathematics, the solid harmonics are solutions of the Laplace equation in spherical polar coordinates. There are two kinds: the regular solid harmonics R^m_\ell(\mathbf{r}), which vanish at the origin and the irregular solid harmonics I^m_{\ell}(\mathbf{r}), which are singular at the origin. Both sets of functions play an important role in potential theory, and are obtained by rescaling spherical harmonics appropriately:

R^m_{\ell}(\mathbf{r}) \equiv \sqrt{\frac{4\pi}{2\ell+1}}\; r^\ell Y^m_{\ell}(\theta,\varphi)

I^m_{\ell}(\mathbf{r}) \equiv \sqrt{\frac{4\pi}{2\ell+1}} \; \frac{ Y^m_{\ell}(\theta,\varphi)}{r^{\ell+1}}

Derivation, relation to spherical harmonics

Introducing r, θ, and φ for the spherical polar coordinates of the 3-vector r, we can write the Laplace equation in the following form

\nabla^2\Phi(\mathbf{r}) = \left(\frac{1}{r} \frac{\partial^2}{\partial r^2}r - \frac{L^2}{\hbar^2 r^2}\right)\Phi(\mathbf{r}) = 0 , \qquad \mathbf{r} \ne \mathbf{0},

where L2 is the square of the angular momentum operator,

\mathbf{L} = -i\hbar\, (\mathbf{r} \times \mathbf{\nabla}) .

It is known that spherical harmonics Yml are eigenfunctions of L2:

L^2 Y^m_{\ell}\equiv \left[ L^2_x +L^2_y+L^2_z\right]Y^m_{\ell} = \hbar^2 \ell(\ell+1) Y^m_{\ell}.

Substitution of Φ(r) = F(r) Yml into the Laplace equation gives, after dividing out the spherical harmonic function, the following radial equation and its general solution,

\frac{1}{r}\frac{\partial^2}{\partial r^2}r F(r) = \frac{\ell(\ell+1)}{r^2} F(r) \Longrightarrow F(r) = A r^\ell + B r^{-\ell-1}.

The particular solutions of the total Laplace equation are regular solid harmonics:

R^m_{\ell}(\mathbf{r}) \equiv \sqrt{\frac{4\pi}{2\ell+1}}\; r^\ell Y^m_{\ell}(\theta,\varphi), and irregular solid harmonics:

I^m_{\ell}(\mathbf{r}) \equiv \sqrt{\frac{4\pi}{2\ell+1}} \; \frac{ Y^m_{\ell}(\theta,\varphi)}{r^{\ell+1}} .

Racah's normalization

Racah's normalization (also known as Schmidt's semi-normalization) is applied to both functions

\int_{0}^{\pi}\sin\theta\, d\theta \int_0^{2\pi} d\varphi\; R^m_{\ell}(\mathbf{r})^*\; R^m_{\ell}(\mathbf{r}) = \frac{4\pi}{2\ell+1} r^{2\ell} (and analogously for the irregular solid harmonic) instead of normalization to unity. This is convenient because in many applications the Racah normalization factor appears unchanged throughout the derivations.

Addition theorems

The translation of the regular solid harmonic gives a finite expansion,

R^m_\ell(\mathbf{r}+\mathbf{a}) = \sum_{\lambda=0}^\ell\binom{2\ell}{2\lambda}^{1/2} \sum_{\mu=-\lambda}^\lambda R^\mu_{\lambda}(\mathbf{r}) R^{m-\mu}_{\ell-\lambda}(\mathbf{a})\;

\langle \lambda, \mu; \ell-\lambda, m-\mu| \ell m \rangle, where the Clebsch-Gordan coefficient is given by

\langle \lambda, \mu; \ell-\lambda, m-\mu| \ell m \rangle = \binom{\ell+m}{\lambda+\mu}^{1/2} \binom{\ell-m}{\lambda-\mu}^{1/2} \binom{2\ell}{2\lambda}^{-1/2}.

The similar expansion for irregular solid harmonics gives an infinite series,

I^m_\ell(\mathbf{r}+\mathbf{a}) = \sum_{\lambda=0}^\infty\binom{2\ell+2\lambda+1}{2\lambda}^{1/2} \sum_{\mu=-\lambda}^\lambda R^\mu_{\lambda}(\mathbf{r}) I^{m-\mu}_{\ell+\lambda}(\mathbf{a})\;

\langle \lambda, \mu; \ell+\lambda, m-\mu| \ell m \rangle with |r| \le |a|\,. The quantity between pointed brackets is again a Clebsch-Gordan coefficient,

\langle \lambda, \mu; \ell+\lambda, m-\mu| \ell m \rangle = (-1)^{\lambda+\mu}\binom{\ell+\lambda-m+\mu}{\lambda+\mu}^{1/2} \binom{\ell+\lambda+m-\mu}{\lambda-\mu}^{1/2} \binom{2\ell+2\lambda+1}{2\lambda}^{-1/2}.

References

The addition theorems were proved in different manners by many different workers. See for two different proofs for example:

  • R. J. A. Tough and A. J. Stone, J. Phys. A: Math. Gen. Vol. 10, p. 1261 (1977)
  • M. J. Caola, J. Phys. A: Math. Gen. Vol. 11, p. L23 (1978)

Real form

By a simple linear combination of solid harmonics of ±m these functions are transformed into real functions. The real regular solid harmonics, expressed in cartesian coordinates, are homogeneous polynomials of order l in x, y, z. The explicit form of these polynomials is of some importance. They appear, for example, in the form of spherical atomic orbitals and real multipole moments. The explicit cartesian expression of the real regular harmonics will now be derived.

Linear combination

We write in agreement with the earlier definition

R_\ell^m(r,\theta,\varphi) = (-1)^{(m+|m|)/2}\; r^\ell \;\Theta_{\ell}^{|m|} (\cos\theta)

e^{im\varphi}, \qquad -\ell \le m \le \ell,

with

\Theta_{\ell}^m (\cos\theta) \equiv \left[\frac{(\ell-m)!}{(\ell+m)!}\right]^{1/2} \,\sin^m\theta\, \frac{d^m P_\ell(\cos\theta)}{d\cos^m\theta}, \qquad m\ge 0, where P_\ell(\cos\theta) is a Legendre polynomial of order l. The m dependent phase is known as the Condon-Shortley phase.

The following expression defines the real regular solid harmonics:

\begin{pmatrix} C_\ell^{m} \\ S_\ell^{m} \end{pmatrix} \equiv \sqrt{2} \; r^\ell \; \Theta^{m}_\ell \begin{pmatrix} \cos m\varphi\\ \sin m\varphi \end{pmatrix} = \frac{1}{\sqrt{2}} \begin{pmatrix} (-1)^m & \quad 1 \\ -(-1)^m i & \quad i \end{pmatrix} \begin{pmatrix} R_\ell^{m} \\ R_\ell^{-m} \end{pmatrix}, \qquad m > 0. and for m = 0:

C_\ell^{0} \equiv R_\ell^{0} . Since the transformation is by a unitary matrix the normalization of the real and the complex solid harmonics is the same.

z-dependent part

Upon writing u = cos θ the mth derivative of the Legendre polynomial can be written as the following expansion in u

\frac{d^m P_\ell(u)}{du^m} = \sum_{k=0}^{\left \lfloor (\ell-m)/2\right \rfloor} \gamma^{(m)}_{\ell k}\; u^{\ell-2k-m} with

\gamma^{(m)}_{\ell k} = (-1)^k 2^{-\ell} \binom{\ell}{k}\binom{2\ell-2k}{\ell} \frac{(\ell-2k)!}{(\ell-2k-m)!}. Since z = r cosθ it follows that this derivative, times an appropriate power of r, is a simple polynomial in z,

\Pi^m_\ell(z)\equiv r^{\ell-m} \frac{d^m P_\ell(u)}{du^m} = \sum_{k=0}^{\left \lfloor (\ell-m)/2\right \rfloor} \gamma^{(m)}_{\ell k}\; r^{2k}\; z^{\ell-2k-m}.

(x,y)-dependent part

Consider next, recalling that x = r sinθcosφ and y = r sinθsinφ,

r^m \sin^m\theta \cos m\varphi = \frac{1}{2} \left[ (r \sin\theta e^{i\varphi})^m + (r \sin\theta e^{-i\varphi})^m \right] = \frac{1}{2} \left[ (x+iy)^m + (x-iy)^m \right] Likewise

r^m \sin^m\theta \sin m\varphi = \frac{1}{2i} \left[ (r \sin\theta e^{i\varphi})^m - (r \sin\theta e^{-i\varphi})^m \right] = \frac{1}{2i} \left[ (x+iy)^m - (x-iy)^m \right]. Further

A_m(x,y) \equiv \frac{1}{2} \left[ (x+iy)^m + (x-iy)^m \right]= \sum_{p=0}^m \binom{m}{p} x^p y^{m-p} \cos (m-p) \frac{\pi}{2} and

B_m(x,y) \equiv \frac{1}{2i} \left[ (x+iy)^m - (x-iy)^m \right]= \sum_{p=0}^m \binom{m}{p} x^p y^{m-p} \sin (m-p) \frac{\pi}{2}.

In total

C^m_\ell(x,y,z) = \left[\frac{(2-\delta_{m0}) (\ell-m)!}{(\ell+m)!}\right]^{1/2} \Pi^m_{\ell}(z)\;A_m(x,y),\qquad m=0,1, \ldots,\ell

S^m_\ell(x,y,z) = \left[\frac{2 (\ell-m)!}{(\ell+m)!}\right]^{1/2} \Pi^m_{\ell}(z)\;B_m(x,y) ,\qquad m=1,2,\ldots,\ell.

List of lowest functions

We list explicitly the lowest functions up to and including l = 5 . Here \bar{\Pi}^m_\ell(z) \equiv \left[\tfrac{(2-\delta_{m0}) (\ell-m)!}{(\ell+m)!}\right]^{1/2} \Pi^m_{\ell}(z) .


\begin{align}
\bar{\Pi}^0_0 & = 1   &
     \bar{\Pi}^1_3 & = \frac{1}{4}\sqrt{6}(5z^2-r^2)  &
           \bar{\Pi}^4_4 & = \frac{1}{8}\sqrt{35}  \\
\bar{\Pi}^0_1 & = z   &
     \bar{\Pi}^2_3 & = \frac{1}{2}\sqrt{15}\; z    &
           \bar{\Pi}^0_5 & = \frac{1}{8}z(63z^4-70z^2r^2+15r^4) \\
\bar{\Pi}^1_1 & = 1   &
     \bar{\Pi}^3_3 & = \frac{1}{4}\sqrt{10}        &
           \bar{\Pi}^1_5 & = \frac{1}{8}\sqrt{15} (21z^4-14z^2r^2+r^4) \\
\bar{\Pi}^0_2 & = \frac{1}{2}(3z^2-r^2) &
     \bar{\Pi}^0_4 & = \frac{1}{8}(35 z^4-30 r^2 z^2 +3r^4 ) &
           \bar{\Pi}^2_5 & = \frac{1}{4}\sqrt{105}(3z^2-r^2)z \\
\bar{\Pi}^1_2 & = \sqrt{3}z &
     \bar{\Pi}^1_4 & = \frac{\sqrt{10}}{4} z(7z^2-3r^2) &
           \bar{\Pi}^3_5 & = \frac{1}{16}\sqrt{70} (9z^2-r^2) \\
\bar{\Pi}^2_2 & = \frac{1}{2}\sqrt{3}  &
     \bar{\Pi}^2_4 & = \frac{1}{4}\sqrt{5}(7z^2-r^2)  &
           \bar{\Pi}^4_5 & = \frac{3}{8}\sqrt{35} z  \\
\bar{\Pi}^0_3 & = \frac{1}{2} z(5z^2-3r^2) &
     \bar{\Pi}^3_4 & = \frac{1}{4}\sqrt{70}\;z  &
           \bar{\Pi}^5_5 & = \frac{3}{16}\sqrt{14} \\
\end{align}


The lowest functions A_m(x,y)\, and B_m(x,y)\, are:

m Am Bm
0 1\, 0\,
1 x\, y\,
2 x^2-y^2\, 2xy\,
3 x^3-3xy^2\, 3x^2y -y^3\,
4 x^4 - 6x^2 y^2 +y^4\, 4x^3y-4xy^3\,
5 x^5-10x^3y^2+ 5xy^4\, 5x^4y -10x^2y^3+y^5\,

Examples

Thus, for example, the angular part of one of the nine normalized spherical g atomic orbitals is:

C^2_4(x,y,z) = \sqrt{\frac{9}{4\pi}} \sqrt{\frac{5}{16}} (7z^2-r^2)(x^2-y^2). One of the 7 components of a real multipole of order 3 (octupole) of a system of N charges qi is

S^1_3(x,y,z) = \frac{1}{4}\sqrt{6}\sum_{i=1}^N q_i (5z_i^2-r_i^2) y_i .

Spherical harmonics in Cartesian form

The following expresses normalized spherical harmonics in Cartesian coordinates (Condon-Shortley phase):

r^\ell\, \begin{pmatrix}

Y_\ell^{m} \\
Y_\ell^{-m}

\end{pmatrix} = \left[\frac{2\ell+1}{4\pi}\right]^{1/2} \bar{\Pi}^m_\ell(z) \begin{pmatrix} (-1)^m (A_m + i B_m) \\ \qquad (A_m - i B_m) \\ \end{pmatrix} , \qquad m > 0. and for m = 0:

r^\ell\,Y_\ell^{0} \equiv \sqrt{\frac{2\ell+1}{4\pi}} \bar{\Pi}^0_\ell . Here

A_m(x,y) = \sum_{p=0}^m \binom{m}{p} x^p y^{m-p} \cos ((m-p) \frac{\pi}{2}),

B_m(x,y) = \sum_{p=0}^m \binom{m}{p} x^p y^{m-p} \sin ((m-p) \frac{\pi}{2}), and for m > 0:

\bar{\Pi}^m_\ell(z) = \left[\frac{(\ell-m)!}{(\ell+m)!}\right]^{1/2} \sum_{k=0}^{\left \lfloor (\ell-m)/2\right \rfloor}

(-1)^k 2^{-\ell} \binom{\ell}{k}\binom{2\ell-2k}{\ell} \frac{(\ell-2k)!}{(\ell-2k-m)!}

\; r^{2k}\; z^{\ell-2k-m}. For m = 0:

\bar{\Pi}^0_\ell(z) == \sum_{k==0}^{\left \lfloor \ell/2\right \rfloor}

(-1)^k 2^{-\ell} \binom{\ell}{k}\binom{2\ell-2k}{\ell} \; r^{2k}\; z^{\ell-2k}.

Examples

Using the expressions for \bar{\Pi}^\ell_m(z), A_m(x,y)\,, and B_m(x,y)\, listed explicitly above we obtain:

Y^1_3 = - \frac{1}{r^3} \left[\tfrac{7}{4\pi}\cdot \tfrac{3}{16} \right]^{1/2} (5z^2-r^2)(x+iy) =

- \left[\tfrac{7}{4\pi}\cdot \tfrac{3}{16}\right]^{1/2} (5\cos^2\theta-1) (\sin\theta e^{i\varphi})

Y^{-2}_4 = \frac{1}{r^4} \left[\tfrac{9}{4\pi}\cdot\tfrac{5}{32}\right]^{1/2}(7z^2-r^2) (x-iy)^2 = \left[\tfrac{9}{4\pi}\cdot\tfrac{5}{32}\right]^{1/2}(7 \cos^2\theta -1) (\sin^2\theta e^{-2 i \varphi}) It may be verified that this agrees with the function listed here and here.

This article was sourced from Creative Commons Attribution-ShareAlike License; additional terms may apply. World Heritage Encyclopedia content is assembled from numerous content providers, Open Access Publishing, and in compliance with The Fair Access to Science and Technology Research Act (FASTR), Wikimedia Foundation, Inc., Public Library of Science, The Encyclopedia of Life, Open Book Publishers (OBP), PubMed, U.S. National Library of Medicine, National Center for Biotechnology Information, U.S. National Library of Medicine, National Institutes of Health (NIH), U.S. Department of Health & Human Services, and USA.gov, which sources content from all federal, state, local, tribal, and territorial government publication portals (.gov, .mil, .edu). Funding for USA.gov and content contributors is made possible from the U.S. Congress, E-Government Act of 2002.
 
Crowd sourced content that is contributed to World Heritage Encyclopedia is peer reviewed and edited by our editorial staff to ensure quality scholarly research articles.
 
By using this site, you agree to the Terms of Use and Privacy Policy. World Heritage Encyclopedia™ is a registered trademark of the World Public Library Association, a non-profit organization.