World Library  
Flag as Inappropriate
Email this Article

Water dimer

Article Id: WHEBN0004186087
Reproduction Date:

Title: Water dimer  
Author: World Heritage Encyclopedia
Language: English
Subject: Water cluster, Dimer (chemistry), Cluster chemistry, Water model, Catalysis
Collection: Cluster Chemistry, Dimers (Chemistry), Forms of Water, Water Chemistry
Publisher: World Heritage Encyclopedia

Water dimer

Ball-and-stick model of the linear water dimer

The water dimer consists of two water molecules loosely bound by a hydrogen bond. It is the smallest water cluster. Because it is the simplest model system for studying hydrogen bonding in water, it has been the target of so many theoretical [1][2][3] (and later experimental) studies that it has been called "a theoretical Guinea pig".[4]

Structure and properties

The ab initio binding energy between the two water molecules is estimated to be 5-6 kcal/mol, although values between 3 and 8 have been obtained depending on the method. The experimentally measured dissociation energy (including nuclear quantum effects) of (H2O)2 and (D2O)2 are 3.16 ± 0.03 kcal/mol (13.22 ± 0.12 kJ/mol)[5] and 3.56 ± 0.03 kcal/mol (14.88 ± 0.12 kJ/mol),[6] respectively. The values are in excellent agreement with calculations.[7][8] The O-O distance of the vibrational ground-state is experimentally measured at ca. 2.98 Å;[9] the hydrogen bond is almost linear, but the angle with the plane of the acceptor molecule is about 57°. The vibrational ground-state is known as the linear water dimer (shown in the figure to the right), which is a near prolate top (viz., in terms of rotational constants, A > B ≈ C). Other configurations of interest include the cyclic dimer and the bifurcated dimer.

History and relevance

The first theoretical study of the water dimer was an ab initio calculation published in 1968 by Morokuma and Pedersen.[10] Since then, the water dimer has been the focus of sustained interest by theoretical chemists concerned with hydrogen bonding—a search of the CAS database up to 2006 returns over 1100 related references (73 of them in 2005). The water dimer is a hotly studied topic in Physical Chemistry for several reasons. (H2O)2 is thought to play a significant role in many atmospheric processes, including acid rain formation, absorption of excess solar radiation, condensation of water droplets, and chemical reactions. In addition, a complete understanding of the water dimer is thought to play a key role in a more thorough understanding of hydrogen bonding in liquid and solid forms of water.


  1. ^ Buckingham, A. D. The hydrogen bond, and the structure and properties of water and the water dimer. Journal of Molecular Structure 1991, 250, 111-18.
  2. ^ Goldman, N., Leforestier, C., and Saykally, R. J., Water Dimers in the Atmosphere II: Results from the VRT(ASP-W)III Potential Surface, Journal of Physical Chemistry A, 2004, 108, p. 787-794.
  3. ^ Schütz, M.; Brdarski, S.; Widmark, P.-O.; Lindh, R.; Karlström, G. The water dimer interaction energy: Convergence to the basis set limit at the correlated level, Journal Chemical Physics, 1997, 107, 4597-4605.
  4. ^ Jeffrey, G. A.; An Introduction to Hydrogen Bonding (Topics in Physical Chemistry). Oxford University Press, USA (March 13, 1997). ISBN 0-19-509549-9
  5. ^ Rocher-Casterline, B. E.; Ch'ng, L. C.; Mollner, A. K.; Reisler, H. Journal of Chemical Physics 2011, 115, 6903-6909 doi:10.1063/1.3598339
  6. ^ Ch'ng, L. C.; Samanta, A. K.; Czakó, G.; Bowman, J. M.; Reisler, H. Journal of American Chemical Society 2012, 134, 15430 doi:10.1021/ja305500x
  7. ^ Shank, A.; Wang, Y.; Kaledin, A.; Braams, B. J.; Bowman. J. M. Journal of Chemical Physics 2009, 130, 144314 doi:10.1063/1.3112403
  8. ^ Leforestier, C.; Szalewicz, K.; van der Avoird, A. Journal of Chemical Physics 2012, 137, 014305 doi:10.1063/1.4722338
  9. ^ Scheiner, S. Ab initio studies of hydrogen bonds: the water dimer paradigm. Annual Review of Physical Chemistry 1994, 45, 23-56.
  10. ^ Morokuma, K.; Pedersen, L. Molecular-orbital studies of hydrogen bonds. An ab initio calculation for dimeric water. Journal of Chemical Physics 1968, 48, 3275-3282.
This article was sourced from Creative Commons Attribution-ShareAlike License; additional terms may apply. World Heritage Encyclopedia content is assembled from numerous content providers, Open Access Publishing, and in compliance with The Fair Access to Science and Technology Research Act (FASTR), Wikimedia Foundation, Inc., Public Library of Science, The Encyclopedia of Life, Open Book Publishers (OBP), PubMed, U.S. National Library of Medicine, National Center for Biotechnology Information, U.S. National Library of Medicine, National Institutes of Health (NIH), U.S. Department of Health & Human Services, and, which sources content from all federal, state, local, tribal, and territorial government publication portals (.gov, .mil, .edu). Funding for and content contributors is made possible from the U.S. Congress, E-Government Act of 2002.
Crowd sourced content that is contributed to World Heritage Encyclopedia is peer reviewed and edited by our editorial staff to ensure quality scholarly research articles.
By using this site, you agree to the Terms of Use and Privacy Policy. World Heritage Encyclopedia™ is a registered trademark of the World Public Library Association, a non-profit organization.

Copyright © World Library Foundation. All rights reserved. eBooks from Project Gutenberg are sponsored by the World Library Foundation,
a 501c(4) Member's Support Non-Profit Organization, and is NOT affiliated with any governmental agency or department.