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Plumbocene

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Title: Plumbocene  
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Plumbocene

Plumbocene
Identifiers
CAS number
Properties
Molecular formula C10H10Pb
Molar mass 337.39 g mol−1
Boiling point 150 °C at 10−7 mmHg[1]
Except where noted otherwise, data are given for materials in their standard state (at 25 °C (77 °F), 100 kPa)
 YesY   YesY/N?)

Plumbocene is an lead. It is a member of the class of metallocenes. It is soluble in benzene, acetone, ether, and petroleum ether, and insoluble in water. Plumbocene is stable in cold water.[1]

Plumbocene is not commercially available. It may be synthesized by the reaction of sodium cyclopentadienide with a lead(II) source such as lead(II) nitrate[1] or lead(II) iodide.[2]

The decamethyl analog, Cp*2Pb, and the half-sandwich complexes, Cp*PbBF4 and Cp*PbCl, are known as well.[3]

References

  1. ^ a b c  
  2. ^ Izod, Keith; McFarlane, William; Wills, Corinne; Clegg, William; Harrington, Ross W. (2008). "Agostic-Type…Pb Interactions Stabilize a Dialkylplumbylene. Structure of and Bonding in [{nPr2P(BH3)}(Me3Si)C(CH2)]2Pb".  
  3. ^ Jutzi, Peter; Dickbreder, Reiner; Nöth, Heinrich (1989). "Blei(II)-Verbindungen mit π-gebundenen Pentamethylcyclopentadienylliganden – Synthesen, Strukturen und Bindungsverhältnisse". Chemische Berichte 122 (5): 865.  
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